73396-94-8Relevant academic research and scientific papers
Insertion Reaction of 2-Halo- N -allylanilines with K 2S Involving Trisulfur Radical Anion: Synthesis of Benzothiazole Derivatives under Transition-Metal-Free Conditions
Liu, Xin-Yu,Zhao, Yan-Wei,Jiang, Tian,Rao, Weidong,Wang, Shun-Yi
, p. 971 - 977 (2020/12/28)
A synthesis of benzothiazole derivatives through the reaction of 2-halo- N -allylanilines with K 2S in DMF is developed. The trisulfur radical anion S 3· -, which is generated in situ from K 2S in DMF, initiates
Microwave-Assisted Domino Heck Cyclization and Phosphorylation: Synthesis of Phosphorus Containing Heterocycles
Ramesh, Karu,Satyanarayana, Gedu
supporting information, p. 3856 - 3866 (2019/06/21)
A domino [Pd]-catalyzed intramolecular Heck cyclization followed by intermolecular phosphorylation, for the construction of phosphorus containing heterocyclic compounds, is presented. Notably, the process is accelerated by microwave heating conditions and enabled the construction of C–C and C–P bonds in short reaction times.
Microwave-Assisted Domino Palladium Catalysis in Water: A Diverse Synthesis of 3,3′-Disubstituted Heterocyclic Compounds
Ramesh, Karu,Basuli, Suchand,Satyanarayana, Gedu
supporting information, p. 2171 - 2177 (2018/05/14)
An environmentally benign microwave-assisted domino [Pd]-catalyzed reaction, for the efficient and diverse synthesis of 3,3′-disubstituted indolines, oxindoles, and dihydrobenzofurans, is presented. Significantly, water served as the sole green solvent and the strategy displayed an excellent functional-group tolerance. Remarkably, the process was also amenable to unmasked functional groups and furnished the products, in very good to almost quantitative yields.
