73396-95-9Relevant academic research and scientific papers
Insertion Reaction of 2-Halo- N -allylanilines with K 2S Involving Trisulfur Radical Anion: Synthesis of Benzothiazole Derivatives under Transition-Metal-Free Conditions
Liu, Xin-Yu,Zhao, Yan-Wei,Jiang, Tian,Rao, Weidong,Wang, Shun-Yi
, p. 971 - 977 (2020/12/28)
A synthesis of benzothiazole derivatives through the reaction of 2-halo- N -allylanilines with K 2S in DMF is developed. The trisulfur radical anion S 3· -, which is generated in situ from K 2S in DMF, initiates
One-pot N-alkylation/Heck approach to substituted indoles
Weinrich, Melissa L.,Beck, Hilary P.
scheme or table, p. 6968 - 6972 (2010/02/27)
Here, we report the palladium-catalyzed one-pot N-alkylation/Heck cyclization of anilines to substituted indoles employing Pd(OAc)2/XPhos. The scope and limitations of this methodology will be described.
