73406-27-6Relevant articles and documents
The First Isolated Sulfinylcarboxylate; Crystal and Molecular Structure
Walter, Wolfgang,Krische, Bernd,Adiwidjaja, Gunadi
, p. 14 - 27 (2007/10/02)
Cyclic Sulfinylcarboxylates 2 are formed from corresponding sulfenylcarboxylates 1 by oxidation with 3-chloroperbenzoic acid.The structure of 2e has been determined from X-ray data and refined to R = 0.06. 2e crystallizes in the monoclinic system, space group P21/c.With exception of the exocyclic sulfinyl oxygen the molecule is nearly planar and reveals only a small amount of no-bond resonance compared with the sulfenylcarboxylate 1e.