73452-11-6

Basic information

• Product Name: Stannane, trimethyl(phenylacetyl)-
• CAS NO: 73452-11-6
• Molecular Formula: C11H16OSn
• Molecular Weight: 282.957
• Mol File: 73452-11-6.mol

Chemical Properties

• CAS DataBase Reference: Stannane, trimethyl(phenylacetyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, trimethyl(phenylacetyl)-(73452-11-6)
• EPA Substance Registry System: Stannane, trimethyl(phenylacetyl)-(73452-11-6)

Safety Data

• Hazardous Substances Data: 73452-11-6(Hazardous Substances Data)

Upstream product

• 661-69-8 hexamethyldistannane 
• 103-80-0 phenylacetyl chloride 
• 73451-97-5 (E)-1-methoxy-2-phenyl-1-trimethylstannylethane 

Relevant articles and documents

Some further studies on acyltrimethylstannanes

The scope and limitations of the palladium-catalysed preparation of acyltins from ditins and acyl chlorides are discussed in detail.Preliminary studies on the chemistry of acyltrimethylstannanes are described.

Unsaturated Acyl Derivatives of Silicon, Germanium, and Tin from Metalated Enol Ethers

The preparation of 1-lithio derivatives of some conjugated vinyl ethers is described.Reaction of these compounds with the chlorotrimethyl derivatives of silicon, germanium, and tin gives the corresponding metallovinyl ethers in 50-80percent yield.At least in the case of silicon these reactions proceed with retention of stereochemistry.The silyl compounds undergo Z E photoisomerization.Hydrolysis of the ethers in aqueous acetone gives the corresponding acylmetallanes in 60-75percent yield.The metalation and hydrolysis reactions are examined in some detail.The spectral properties of these novel unsaturated acylmetallanes are presented and discussed.