73453-45-9

Basic information

• Product Name: Di-n-hexyl acetylmalonate
• Synonyms: Di-n-hexyl acetylmalonate
• CAS NO: 73453-45-9
• Molecular Weight: 314.422
• Mol File: 73453-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Di-n-hexyl acetylmalonate(CAS DataBase Reference)
• NIST Chemistry Reference: Di-n-hexyl acetylmalonate(73453-45-9)
• EPA Substance Registry System: Di-n-hexyl acetylmalonate(73453-45-9)

Safety Data

• Hazardous Substances Data: 73453-45-9(Hazardous Substances Data)

Upstream product

• 73453-43-7 Ethyl Acetyl-N-cyclohexylmalonamate 

Relevant articles and documents

Reactions of Acetoacetic Ester Blocked Cyclohexyl Isocyanate

Acetoacetic ester has been widely reported to be a blocking agent for isocyanates.However, we find that only a trace of isocyanate is formed by thermolysis of acetoacetic ester blocked cyclohexyl isocyanate, 1, at 150 deg C and atmospheric pressure.The major portion is unchanged even after 8 h, with some conversion to acetylmalonic ester, 2, and acetyl-N,N'-dicyclohexylmalonamide, 3.Alcoholysis does not yield the "normal" urethane as blocked isocyanates do but rather esters of 1 with some diesters of 2 and smaller amounts of 3.Significant amounts of N-cyclohexylacetamide, N-cyclohexylmalonamate ester, and some N,N'-dicyclohexylmalonamide are also obtained.Aminolysis leads to N-substituted acetamides and N-cyclohexylmalonamate but no substituted ureas, the "normal" products for aminolysis of blocked isocyanates.In the presence of acid catalysts, alcoholysis leads to N-cyclohexylmalonamates with acetate esters as the other product.