7348-93-8

Usage

InChI:InChI=1/C6H15OSi.Na/c1-4-8(7,5-2)6-3;/h4-6H2,1-3H3;/q-1;+1

Upstream product

• 597-52-4 Triethylsilanol 
• 994-30-9 triethylsilyl chloride 
• 597-67-1 ethoxytriethylsilane 
• 18056-07-0 Bis sulfate 

Downstream Products

• 33207-06-6 1,1,1-Triethyl-3,3-dimethyl-3-(2-phenylsulfanyl-ethyl)-disiloxane 
• 33207-05-5 C₂₁H₄₂O₂SSi₃ 
• 33207-04-4 C₂₆H₅₄O₃SSi₄ 
• 915939-78-5 (S)-triethyl(1-phenylallyloxy)silane 
• 18547-99-4 phenyl-bis-triethylsilanyloxy-borane 
• 18055-61-3 diphenyl(triethylsiloxy)borane 
• 438188-09-1 Pt((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OSi(CH₂CH₃)3)Cl 
• 438188-08-0 Pt((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(OSi(CH₂CH₃)3)2 

Relevant academic research and scientific papers

Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids

Copper-mediated reductive coupling between CO2 and an aldehyde to form α-hydroxycarboxylic acid was achieved using silylborane as a reductant. CO2 cleanly inserted into a copper-carbon bond that was formed by the reaction between a silylcopper-NHC complex

Preparation and characterization of the rhenium silyl esters (η5-C5Me5)(CO)(NO)ReC(O)OSiR3 (SiR3 = SiMe2Ph, SiEt3)

Three synthetic approaches to the rhenium silyl esters Cp * (CO)(NO)ReC(O)OSiEt3 (3) and Cp * (CO)(NO)ReC(O)OSiMe2Ph (4) were evaluated. (a) Treatment of a CH2Cl2 solution of Cp * (CO)2(NO)Re+BF-4 with a silanolate NaOSiEt3 (5) or NaOSiMe2Ph (6) provided 90% isolated yields of 3 and 4. These stable orange-yellow solids are extremely moisture sensitive: traces of water hydrolyze them to Cp * (CO)(NO)ReCO2H and the parent silanol. IR and NMR spectral data of 3 and 4 are consistent with nonchelating μ(η1-C:η1-O) metalloester structures. Less efficient preparative routes to 3 and 4 include treatment of (b) Cp * (CO)(NO)ReCO2H with the requisite chloroalkylsilane and NiPr2Et, and (c) Cp * (CO)(NO)ReCO-2Na+ (7Na+) with the chloroalkylsilane. The new rhenium CO2 adducts Cp * (CO)(NO)ReCO-2M+ (7Li+, 7Na+) were generated by deprotonation of Cp * (CO)(NO)ReCO2H with excess LiH or NaH THF suspensions at 0°C. Both 7Li+ and 7Na+ were characterized by their solution IR spectra and by the formation of their derivatives with silyl and tin chlorides.