73499-25-9Relevant articles and documents
5-(β-Cyclodextrinylamino)-5-deoxy-α-D-riboses as models for nuclease, ligase, phosphatase, and phosphorylase
Han, Man Jung,Yoo, Kyung Soo,Chang, Ji Young,Ha, Tae-Kyu
, p. 347 - 349 (2000)
β-Cyclodextrin derivatives crowned with ribose rings (such as 1) catalyzed the hydrolysis, esterification, and phosphorylation of catechol- derived phosphate esters. The vicinal cis-diols on the ribose groups appear to play a major role in the catalytic activity of these enzyme models by the formation of hydrogen bonds which activate the phosphorus atom to nucleophilic attack.
Proton Inventory of a Bifunctional Ribonuclease Model
Anslyn, Eric,Breslow, Ronald
, p. 8931 - 8932 (1989)
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