7355-20-6Relevant academic research and scientific papers
Solvent-free synthesis of 4,4-diaminotriarylmethanes-leuco malachite materials in the presence of FePO4
Behbahani, Farahnaz K.,Khademloo, Elham
, p. 1507 - 1510 (2015/02/05)
A fast, efficient and versatile route for the synthesis of 4,4-diaminotriarylmethanes is reported using N,N-dimethyl aniline and aryl aldehydes in presence of FePO4 under solvent-free condition at 100°C.
SbCl3-catalyzed one-pot synthesis of 4,4′-diamino- triarylmethanes under solvent-free conditions: Synthesis, characterization, and DFT studies
Bardajee, Ghasem Rezanejade
experimental part, p. 135 - 144 (2011/05/16)
A simple, efficient, and mild procedure for a solvent-free one-step synthesis of various 4,4′-diaminotriarylmethane derivatives in the presence of antimony trichloride as catalyst is described. Triarylmethane derivatives were prepared in good to excellent yields and characterized by elemental analysis, FTIR, 1H and 13C NMR spectroscopic techniques. The structural and vibrational analysis were investigated by performing theoretical calculations at the HF and DFT levels of theory by standard 6-31Gs *, 6-31G*/B3LYP, and B3LYP/cc-pVDZ methods and good agreement was obtained between experimental and theoretical results.
