73562-83-1Relevant articles and documents
HALOGEN EXCHANGE EQUILIBRIA OF CHLOROFLUOROOLEFINS
Coulson, D. Robert
, p. 77 - 87 (2007/10/02)
The thermochemical properties of the following reactions were determined using either AlF3 or Cr2O3 as catalysts: (1) (2) (3) In addition, the cis-trans equilibria of both CF3CF=CFCl and CF3CCl=CFCl were able to be derived from the reaction data.The experimental thermochemical properties for reactions (1), (2) and (3) were compared with property values calculated using a well-known approximation method.A study of the exchange equilibria of chlorofluoroethylenes failed to yield accurate thermochemical values due to significant side reactions.However, a brief study of the mechanism of a catalytic disproportionation of CF2=CFCl: was carried out.