7361-94-6

Basic information

• Product Name: Phenol, 2-(2,3-dihydro-2-benzothiazolyl)-
• CAS NO: 7361-94-6
• Molecular Formula: C13H11NOS
• Molecular Weight: 229.302
• Mol File: 7361-94-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(2,3-dihydro-2-benzothiazolyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(2,3-dihydro-2-benzothiazolyl)-(7361-94-6)
• EPA Substance Registry System: Phenol, 2-(2,3-dihydro-2-benzothiazolyl)-(7361-94-6)

Safety Data

• Hazardous Substances Data: 7361-94-6(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 137-07-5 2-amino-benzenethiol 
• 26907-82-4 2,2'-((1E,1'E)-((disulfanediylbis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenol 
• 1141-88-4 2-Aminophenyl disulfide 

Downstream Products

• 82057-06-5 WOCl₃(OHC₆H₄CHNHC₆H₄S)2 
• 171087-90-4 Co⁽²⁺⁾*C₁₃H₁₀NOS^(1-)*CH₃COO^(1-)*H₂O = Co(C₁₃H₁₀NOS)(CH₃COO)(H₂O) 
• 171087-91-5 Co⁽³⁺⁾*C₁₃H₁₀NOS^(1-)*C₁₃H₉NOS^(2-)*H₂O = Co(C₁₃H₁₀NOS)(C₁₃H₉NOS)(H₂O) 
• 3411-95-8 2-(benzothiazol-2-yl)phenol 
• 171087-92-6 Co⁽²⁺⁾*C₁₃H₉NOS^(2-)*H₂O = Co(C₁₃H₉NOS)(H₂O) 
• 85561-03-1 C₁₃H₉NOSBOB(OCOCH₃)2 
• 86136-58-5 1-(2-{2-[3-(Cyclohexyl-methyl-amino)-propoxy]-phenyl}-benzothiazol-3-yl)-ethanone 
• 112946-52-8 2-{2-[3-(Cyclohexyl-methyl-amino)-propoxy]-phenyl}-benzothiazole-3-carbaldehyde 
• 112947-04-3 1-{2-[2-(2-Dimethylamino-ethoxy)-phenyl]-benzothiazol-3-yl}-ethanone 
• 86135-08-2 3-Acetyl-2-[2-(3-dimethylaminopropoxy)phenyl]benzothiazoline 
• 86135-02-6 3-acetyl-2-<2-<3-(methylamino)propoxy>phenyl>benzothiazoline 
• 112946-99-3 3-acetyl-2-<2-(3,3-diethoxypropoxy)phenyl>benzothiazoline 
• 93264-99-4 1-{2-[2-(4-Chloro-butoxy)-phenyl]-benzothiazol-3-yl}-ethanone 
• 86136-52-9 3-acetyl-2-<2-(3-oxopropoxy)phenyl>benzothiazoline 

Relevant articles and documents

Pentafluorophenylammonium Triflate: A Mild, Efficient and Reusable Catalyst for the Synthesis of 2-Arylbenzothiazole and 2-Arylbenzothiazoline Derivatives in a Green Chemical Approach

In this work, one pot, simple and environmentally benign effective synthesis of 2-substituted benzothiazole and benzothiazoline derivatives are described in presence of PFPAT (pentafluorophenylammonium triflate) catalyst in water successfully. A series of benzothiazole derivative were synthesized by the reaction between 2-aminothiophenol and various aldehydes in good yields. Recyclability of the catalyst is observed for four times without loss of its activity in aqueous medium.

Photoactivated aggregation-inducing luminescent probe having in-situ generation capability and preparation and application thereof

The invention belongs to the technical field of biological imaging, and discloses a photoactivated aggregation-inducing luminescent probe having in-situ generation capability and a preparation and application thereof. The preparation method comprises the following steps: reacting a bis(2-(2--hydroxybenzylidene)amino)aryldisulfide compound with a thiol to obtain the photoactivated aggregation-inducing luminescent probe, which has the structural formula III. The photoactivated aggregation-inducing luminescent probe is gathered in a specific organelle to produce a 2-(2-hydroxyphenyl)benzothiazolecompound having aggregation-inducing luminescent properties by photooxidation. The photoactivated aggregation-inducing luminescent probe having in-situ generation capability can effectively overcomethe defects of aggregation-induced quenching of traditional fluorescent dyes, and realize the organelle-targeting specific photo-activated fluorescence imaging in living cells, and has the advantagesof easy preparation, long-term storage, high light activation efficiency, large Stokes displacement, and strong ability to enter the cells.

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities

The recent disclosures of two classes of acylborons, potassium acyltrifluoroborates (KATs) and N-methyliminodiacetyl (MIDA) acylboronates, demonstrated that certain acylboron species can be both remarkably stable and uniquely reactive. Here we report new classes of ligands for acylboronates that have a significant influence on the formation, properties, and reactivities of acylboronates. Our systematic investigations identified a class of neutral, monofluoroboronates that can be prepared in a one step, gram-scale fashion from readily accessible KATs. These monofluoroboronates are stable to air, moisture, and silica gel chromatography and can be easily handled without any special precautions. X-ray crystallography, NMR spectroscopy, and HPLC studies showed that they are tetravalent, configurationally stable B-chiral acylboronates. Significantly, the ligands on the boronate allow for fine-tuning of the properties and reactivity of acylboronates. In amide-forming ligation with hydroxylamines under aqueous conditions, a considerable difference in reactivity was observed as a function of ligand structure. The solid-state structures suggested that subtle steric and conformational factors modulate the reactivities of the acylboronates.