736137-76-1Relevant academic research and scientific papers
Cationic and neutral four-coordinate alkylidene complexes of vanadium(IV) containing short V=C bonds
Basuli, Falguni,Kilgore, Uriah J.,Hu, Xile,Meyer, Karsten,Pink, Maren,Huffman, John C.,Mindiola, Daniel J.
, p. 3156 - 3159 (2004)
Kinetically stable, four-coordinate vanadium (IV) neopentylidene complexes such as [(Nacnac)V=CHtBu(thf)](BPh4) (Nacnac-=[Ar]NC(Me) CHC(Me)N[Ar], Ar=2,6-(CHMe2)2C6H3), which was prepared by oxidatively induced α-hydrogen abstraction from [(Nacnac)V(CH2tBu)2] with AgBPh4 in THF (see structure), contain the shortest V=C bonds known to date.
