736172-42-2

Basic information

• Product Name: N-(1-(4-bromophenyl)but-3-en-1-yl)-4-methoxybenzenamine
• Synonyms: N-(1-(4-bromophenyl)but-3-en-1-yl)-4-methoxybenzenamine
• CAS NO: 736172-42-2
• Molecular Weight: 332.24
• Mol File: 736172-42-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(1-(4-bromophenyl)but-3-en-1-yl)-4-methoxybenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-(4-bromophenyl)but-3-en-1-yl)-4-methoxybenzenamine(736172-42-2)
• EPA Substance Registry System: N-(1-(4-bromophenyl)but-3-en-1-yl)-4-methoxybenzenamine(736172-42-2)

Safety Data

• Hazardous Substances Data: 736172-42-2(Hazardous Substances Data)

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 28115-12-0 N-(4-bromobenzylidene)-4-methoxyaniline 
• 106-95-6 allyl bromide 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 383-67-5 allyl trifluoroacetate 
• 28115-12-0 (E)-1-(4-bromophenyl)-N-(4-methoxyphenyl)methanimine 

Relevant articles and documents

Asymmetric Petasis Borono-Mannich Allylation Reactions Catalyzed by Chiral Biphenols

Chiral biphenols catalyze the asymmetric Petasis borono-Mannich allylation of aldehydes and amines through the use of a bench-stable allyldioxaborolane. The reaction proceeds via a two-step, one-pot process and requires 2–8 mole % of 3,3′-Ph2-BINOL as the optimal catalyst. Under microwave heating the reaction affords chiral homoallylic amines in excellent yields (up to 99 %) and high enantioselectivies (er up to 99:1). The catalytic reaction is a true multicomponent condensation reaction whereas both the aldehyde and the amine can possess a wide range of structural and electronic properties. Use of crotyldioxaborolane in the reaction results in stereodivergent products with anti- and syn-diastereomers both in good diastereoselectivities and enantioselectivities from the corresponding E- and Z-borolane stereoisomers.

Diene-ligated iridium catalyst for allylation reactions of ketones and imines

[Ir(cod)CI]2 is a highly reactive catalyst for allylation reactions of ketones using allylboronic ester. Mechanistic experiments are consistent with formation of a nucleophilic allyliridium(1) complex that is activated by the diene ligand towar