73619-46-2Relevant academic research and scientific papers
Iridium-Catalyzed Formyl-Selective Deuteration of Aldehydes
Kerr, William J.,Reid, Marc,Tuttle, Tell
, p. 7808 - 7812 (2017)
We report the first direct catalytic method for formyl-selective deuterium labeling of aromatic aldehydes under mild conditions, using an iridium-based catalyst designed to favor formyl over aromatic C?H activation. A good range of aromatic aldehydes is s
SYNTHESIS OF DEUTERATED ALDEHYDES
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Paragraph 0008; 00102, (2021/03/13)
Described are methods for preparing a deuterated aldehyde using N-heterocyclic carbene catalysts in a solvent comprising D2O. The methods may be used to convert a wide variety of aldehydes (e.g., aryl, alkyl, or alkenyl aldehydes) to C-1 deuterated aldehydes under mild reaction conditions without functionality manipulation.
α-(METHYLTHIO)BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART V. SYNTHESES OF SOME o- AND m-SUBSTITUTED 1-DEUTERIOBENZALDEHYDES
Wladislaw, B.,Marzorati, L.,Ebeling, G.
, p. 25 - 28 (2007/10/02)
o- and m-Substituted α-methylthiobenzyl sulfones incorporate deuterium when treated with a base and deuterium oxide.The resulting deuterated sulfones, by thermal decomposition, afford o- and m-substituted 1-deuteriobenzaldehydes in good yields and high is
