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Studies on Terpenes. 8. Total Synthesis of (+/-)-Linderalactone, (+/-)-Isolinderalactone, and (+/-)-Neolinderalactone, Germacrane Furanosesquiterpenes
Gopalan, Aravamuden,Magnus, Philip
, p. 2317 - 2321 (2007/10/02)
The synthesis of linderalactone (1), isolinderalactone (2), and neolinderalactone (3) is described and exploits the unique ability of these fluxional systems to enter into Cope and abnormal Cope rearrangements.The symmetrical β-diketone 10 was converted i
