7370-44-7Relevant articles and documents
Mammalian exocrine secretions: X. Constituents of preorbital secretion of grysbok, Raphicerus melanotis
Burger,Tien,Roux,Mo
, p. 739 - 764 (1996)
Using electron impact and chemical ionization mass spectrometry with methane and nitric oxide as reactant gases in conjunction with mass spectral analysis of the dimethyl disulfide derivatives of unsaturated constituents, 51 compounds have been identified in addition to the compounds previously found in the preorbital secretion of the grysbok Raphicerus melanotis. The compounds identified are saturated, monounsaturated, and diunsaturated alcohols and formates, saturated and monounsaturated aldehydes, saturated carboxylic acids, γ- and δ-lactones, alkyl methyl sulfides, and β-hydroxyalkyl acetates. All of these compounds have unbranched structures. The constituent previously incorrectly identified as (Z)-5-tetradecen-1-ol, was found to consist of the coeluting (Z)-7- and (Z)-8-tetradecenols.
Syntheses of 5-hexadecanolide, 6-acetoxy-5-hexadecanolide and tanikolide
Chang, Meng-Yang,Lin, Chien-Lun,Chen, Shui-Tein
, p. 787 - 794 (2007/10/03)
Total syntheses of 5-hexadecanolide (1), 6-acetoxy-5-hexadecanolide (2) and tanikolide (3) are described. 1-Bromoundecane (4) and 5-benzyl-1-pentanal (5) were chosen as starting materials. Wittig olefination and Grignard addition 4 and 5 afforded the 16-carbon skeleton, which underwent a series of functional group transformations to give δ-lactone derivatives 1, 2 and 3.
Lipase-catalysed Baeyer-Villiger Reactions
Lemoult, Stephanie C.,Richardson, Paul F.,Roberts, Stanley M.
, p. 89 - 92 (2007/10/02)
The Baeyer-Villiger Oxidation of some 2- and 3-substituted cyclopentanones and cyclohexanones using myristic acid and hydrogen peroxide is catalysed by Candida anatarctica lipase.
