73726-79-1Relevant academic research and scientific papers
PHOTOELECTRON SPECTRA OF FURYLSILANES AND THEIR CARBON ANALOGS
Zykov, B.G.,Erchak, N.P.,Khvostenko, V.I.,Lukevits, E.,Matorykina, V.F.,Asfandiarov, N.L.
, p. 301 - 312 (2007/10/02)
The first vertical ?-ionization energies of substituted furans as determined by photoelectron spectroscopy are compared with the results of CNDO/2 calculations.The analysis of the photoelectron spectra and quantum chemical calculations for furylsilanes, difurylsilanes and some carbon analogs has shown the importance of the p?-d? interaction as well as of the conjugation and necessity of the inclusion of silicon d-atomic orbitals into the basic set.
