73732-39-5Relevant academic research and scientific papers
A general method for the formation of aryl-sulfur bonds using copper(I) catalysts.
Bates, Craig G,Gujadhur, Rattan K,Venkataraman
, p. 2803 - 2806 (2002)
[reaction: see text] We report a mild, palladium-free synthetic protocol for the cross-coupling reaction of aryl iodides and thiols using 10 mol % CuI and 10 mol % neocuproine, with NaOt-Bu as the base, in toluene at 110 degrees C. Using this protocol, we have shown that a variety of aryl sulfides can be synthesized in excellent yields from readily available iodides and thiols.
Methods for formation of aryl-sulfur and aryl-selenium compounds using copper(I) catalysts
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Page/Page column 11-12; 32, (2008/06/13)
A mild, palladium-free synthetic protocol for the cross-coupling reaction of vinyl or aryl iodides and thiols or selenols using, in certain embodiments, 10 mol % CuI and 10 mol % neocuproine, with NaOt-Bu as the base, in toluene at 110 ° C. A variety of vinyl/aryl sulfides and vinyl/aryl selenides can be synthesized in excellent yields from readily available iodides and thiols or selenols.
