73733-09-2

Basic information

• Product Name: bicyclo<5.1.0>octan-2-one tosylhydrazone
• Synonyms: bicyclo<5.1.0>octan-2-one tosylhydrazone
• CAS NO: 73733-09-2
• Molecular Weight: 292.402
• Mol File: 73733-09-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bicyclo<5.1.0>octan-2-one tosylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo<5.1.0>octan-2-one tosylhydrazone(73733-09-2)
• EPA Substance Registry System: bicyclo<5.1.0>octan-2-one tosylhydrazone(73733-09-2)

Safety Data

• Hazardous Substances Data: 73733-09-2(Hazardous Substances Data)

Upstream product

• 16335-43-6 bicyclo<5.1.0>octan-2-one 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 695-12-5 vinylcyclohexane 
• 65909-92-4 1-octen-7-yne 
• 37680-26-5 bicyclo<4.2.0>oct-6-ene 
• 111-65-9 octane 
• 278-30-8 bicyclo<4.2.0>octane 
• 1678-91-7 ethyl-cyclohexane 

Relevant articles and documents

EFFECT OF THE STRUCTURE OF BICYCLIC CARBENES ON THE DIRECTION OF THEIR STABILIZATION

By pyrolysis of the sodium salts of bicyclooctan-2-one and bicyclononan-2-one tosylhydrazones the corresponding carbenes were generated.The first of them undergoes fragmentation with the formation of 1-octen-7-yne and rearrangement to bicyclooct-6-ene, and the second rearranges to bicyclodec-8-ene and forms the products from transannular insertion, i.e., tricyclo2,4>decane and tricyclo2,4>decane.The difference in the direction of stabilization in these carbenes is due to the geometry of the arrangement of the three-membered ring in relation to the vacant p orbital.