73739-84-1Relevant academic research and scientific papers
Synthesis and derivatization of bis-nor Wieland-Miescher ketone
Kanger, Tonis,Raudla, Kristin,Aav, Riina,Mueuerisepp, Aleksander-Mati,Pehk, Tonis,Lopp, Margus
, p. 3147 - 3151 (2005)
An efficient synthesis of bis-nor Wieland-Miescher ketone and its derivatives starting from commercially available 2-allyl-2-methylcyclopenta-1,3- dione is described. Georg Thieme Verlag Stuttgart.
Formal Cycloaddition of Molecular Oxygen, 1,3-Diketone, and Olefin. Synthesis and Reactions of Cyclic Peroxides
Yoshida, Jun-ichi,Nakatani, Shogo,Sakaguchi, Kazuhiko,Isoe, Sachihiko
, p. 3383 - 3389 (2007/10/02)
Formal cycloaddition of molecular oxygen, 1,3-diketones, and olefins took place by electrochemical oxidation.A catalytic amount of electricity was sufficient for the reaction, and an electroinitiated radical chain mechanism was proposed.The reaction was also initiated by a radical initiator.The resulting cyclic peroxides reacted with acids and some reducing agents such as ferrous sulfate, thiurea, and copper(I) chloride to give oxygen-oxygen bond cleavage products.
