73752-29-1Relevant academic research and scientific papers
REACTION DES PHOSPHORINES AVEC LES CYMANTRENES. SYNTHESE D'UN COMPLEXE SANDWICH η5-CYCLOPENTADIENYL-η6-PHOSPHORINE-MANGANESE
Nief, Francois,Charrier, Claude,Mathey, Francois,Simalty, Michel
, p. 277 - 286 (2007/10/02)
?-Phosphorin-manganese complexes are easily obtained from RCpMn(CO)2 (THF) and phosphorins.Photolysis of CpMn(CO)2 (triphenylphosphorin) yields a sandwich complex: (η5-cyclopentadienyl)(η6-triphenylphosphorin) manganese, which displays a particularly high field resonance in its 31P NMR spectrum.By photolysis of RCpMn(CO)2(4,5-dimethyl 2-phenylphosphorin), two additionnal products are obtained, to one of which the structure of a ?-? complex has been assigned.
