73766-30-0

Basic information

• Product Name: (R)-(p-Tolyl)-<2-(trimethylsilyloxy)octyl>-sulfoxid
• CAS NO: 73766-30-0
• Molecular Weight: 340.602
• Mol File: 73766-30-0.mol

Chemical Properties

• CAS DataBase Reference: (R)-(p-Tolyl)-<2-(trimethylsilyloxy)octyl>-sulfoxid(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(p-Tolyl)-<2-(trimethylsilyloxy)octyl>-sulfoxid(73766-30-0)
• EPA Substance Registry System: (R)-(p-Tolyl)-<2-(trimethylsilyloxy)octyl>-sulfoxid(73766-30-0)

Safety Data

• Hazardous Substances Data: 73766-30-0(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 111-71-7 heptanal 
• 50921-35-2 (R)-(2-Hydroxyoctyl)-(p-tolyl)-sulfoxid 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 

Downstream Products

• 73766-31-1 (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid 
• 73766-32-2 (R)-(Z-2-Octenyl)-p-tolyl-sulfoxid 
• 61187-68-6 (R)-1-Octenyl-p-tolyl-sulfoxid 

Relevant articles and documents

Stereoselective Synthesis of Alcohols, II Stereochemistry of the Sigmatropic Rearrangement of 3-Substituted 2-Alkenyl Sulfoxides

Rearrangement of the 3-E-substituted allyl sulfoxides 5 to the allyl alcohols 19 and 30 proceeds with low enantiomeric selectivity.In contrast, the 3-Z-substituted allyl sulfoxide 7b rearranged uniformly via the endo-transition state 26.