73766-75-3Relevant academic research and scientific papers
Stereoselective Synthesis of Alcohols, IV Conformational Factors Determining the Stereochemistry of the Allyl Sulfoxide/ Allyl Sulfenate-Rearrangement
Hoffmann, Reinhard W.,Gerlach, Rainer,Goldmann, Siegfried
, p. 856 - 863 (2007/10/02)
The stereochemistry of the sigmatropic rearrangement of the conformationally rigid allyl sulfoxides 5 revealed a 6.2 fold preference for axial formation of the new C-O-bond.This preference dominates the 3.1 fold preference for an exo-versus endo-tran
