73769-50-3Relevant academic research and scientific papers
Studies on the Reactivity of Metal ?-Complexes, XXXI. Dinuclear Palladium(I) Complexes with Bridging Carboxylate Ligands
Werner, Helmut,Kraus, Hans-Juergen
, p. 1072 - 1083 (2007/10/02)
The reaction of 2(OCOR')2 with an equimolar amount of Pd2 in hexane produces in very good yields the dinuclear complexes (2-RC3H4)(OCOR')Pd22 (6, 8, 10) in which palladium has the oxidation state +1.The synthesis of (C5H5)(OCOCH3)Pd22 (15) starts with the diolefin complexes 2(OCOCH3)2 (11) and 2(OCOCH3)2 (12) which react with TlC5H5 to give C5H5Pd(dien)OCOCH3 .The reaction of 13 or 14 with Pd2 gives 15.In the complexes 11 - 14 the diolefin is coordinated only with one C = C bond (dihapto link). - The reaction of Pd(acac)2 with either Pd2 or P(i-C3H7)3 leads to Pd(acac)2P(i-C3H7)3 (17) which contains one O,O-bonded and one C-bonded acetylacetonate ligand.
