73770-60-2Relevant academic research and scientific papers
Rearrangements of Tricyclo3.6>octyl Systems
Sauers, Ronald R.,Weston, Charles A.,Dentz, Bernard I.
, p. 2813 - 2816 (2007/10/02)
New 2,2-substituted derivatives of tricyclo3.6>octane with the following sets of substituents were synthesized in a study designed to test their stability toward Wagner-Meerwein rearrangements: CH3, OH; CH3, Cl; C6H5, OH; Cl, Cl; Br, CO2H.Epimerizations, but not skeletal rearrangements, were observed in some cases.The phenyl carbinol underwent self-reduction under vigorous conditions.
