737784-19-9Relevant academic research and scientific papers
Synthesis, EPR, electrochemistry and EXAFS studies of ruthenium(III) complexes with a symmetrical tetradentate N2O2 Schiff base
Prabhakaran, Rathinasabapathi,Krishnan, Venkata,Geetha, Arumugam,Bertagnolli, Helmut,Natarajan, Karuppannan
, p. 1114 - 1120 (2008/10/09)
A series of new hexa-coordinated ruthenium(III) complexes of the type [RuX(Nap-o-phd)(EPh3)] (where, H2-Nap-o-phd = N,N′-bis(2-hydroxy-1-naphthaldehyde) o-phenylene diamine; X = Cl or Br; E = P or As) have been prepared by reacting [RuX3(EPh3) 3] and [RuBr3(PPh3)2(MeOH)] (where X = Cl or Br; E = P or As) with tetradentate Schiff base ligand (H 2-Nap-o-phd) in 1:1 molar ratio. The complexes have been characterized by elemental analyses, infra red, electronic, electron paramagnetic resonance spectroscopy and cyclic voltammetry. The coordination geometry and structure of the complexes have been investigated by extended X-ray absorption fine structure (EXAFS) spectroscopy and an octahedral structure has been proposed.
Spectral and catalytic studies of ruthenium(III) Schiff base complexes
Ramesh
, p. 274 - 276 (2008/10/09)
Twelve low spin ruthenium(III) Schiff base complexes of the type [RuX(EPh3) (LL′)] (where X=Cl or Br; E=P or As; LL′=dibasic tetradentate Schiff base) were synthesized and characterized. These complexes catalyze oxidation of primary alcohol wit
