73789-60-3Relevant academic research and scientific papers
Metal Complexes of Functional Isocyanides, VIII: (Isocyanoimino)triphenylphosphorane Metal Complexes
Weinberger, Bernd,Fehlhammer, Wolf Peter
, p. 42 - 50 (2007/10/02)
The thermally unusually stable N-isocyanide CNNPPh3 (1) is prepared by the reaction of formylhydrazine with triphenylphosphane, tetrachloromethane, and triethylamine and reacted with metal compounds to give the complexes M(CO)5CNNPPh3 (M = Cr, Mo, W) (3-5), cis-Cr(CO)4(CNNPPh3)2 (6), Mn(η-C5H5)(CO)2CNNPPh3 (7), PF6 (8), PdX2(CNNPPh3)2 (X = Cl, I) (9a,b), cis-BF4 (11), and trans-2 (12).
