73804-82-7Relevant academic research and scientific papers
Reactions of bis(trimethylsilyl)isocyanamide and its isomers with chlorotriphenylphosphonium chloride: evidence for a transient dizomethylenetriphenylphosphorane. Crystal structure of NN->2
Zinner, Gerhard,Beck, Gerhard,Fehlhammer, Wolf P.,Wiberg, Nils
, p. 23 - 30 (1989)
Triphenylphosphine dichloride reacts with (Me3Si)2C=NN, Me3SiN=C=NSiMe3, and metal-coordinated CN-N(SiMe3)2 to give the iminophosphoranes CN-NPPh3, NC-NPPh3, and W(CO)5CN-NPPh3, respectively, and with free bis(trimethylsilyl)isocyanamine to give a dicatio
Metal Complexes of Functional Isocyanides, VIII: (Isocyanoimino)triphenylphosphorane Metal Complexes
Weinberger, Bernd,Fehlhammer, Wolf Peter
, p. 42 - 50 (2007/10/02)
The thermally unusually stable N-isocyanide CNNPPh3 (1) is prepared by the reaction of formylhydrazine with triphenylphosphane, tetrachloromethane, and triethylamine and reacted with metal compounds to give the complexes M(CO)5CNNPPh3 (M = Cr, Mo, W) (3-5), cis-Cr(CO)4(CNNPPh3)2 (6), Mn(η-C5H5)(CO)2CNNPPh3 (7), PF6 (8), PdX2(CNNPPh3)2 (X = Cl, I) (9a,b), cis-BF4 (11), and trans-2 (12).
