73880-61-2

Upstream product

• 73766-74-2 Dimethyl-[2-((S)-3,3,5,5-tetramethyl-cyclohexylidenemethanesulfinyl)-benzyl]-amine 
• 73880-60-1 Dimethyl-[2-((S)-3,3,5,5-tetramethyl-cyclohex-1-enylmethanesulfinyl)-benzyl]-amine 
• 73880-58-7 <2-(Dimethylaminomethyl)phenyl>-<(3,3,5,5-tetramethyl-1-trimethylsilyloxycyclohexyl)methyl>-sulfoxid 
• 73880-57-6 <2-(Dimethylaminomethyl)phenyl>-<(1-hydroxy-3,3,5,5-tetramethylcyclohexyl)methyl>-sulfoxid 
• 73880-59-8 <2-(Dimethylaminomethyl)phenyl>-<(3,3,5,5-tetramethylcyclohexyliden)methyl>-sulfoxid 
• 73880-60-1 Dimethyl-[2-(3,3,5,5-tetramethyl-cyclohex-1-enylmethanesulfinyl)-benzyl]-amine 
• 14376-79-5 3,3,5,5-tetramethylcyclohexanone 

Relevant academic research and scientific papers

Stereoselective Synthesis of Alcohols, IV Conformational Factors Determining the Stereochemistry of the Allyl Sulfoxide/ Allyl Sulfenate-Rearrangement

The stereochemistry of the sigmatropic rearrangement of the conformationally rigid allyl sulfoxides 5 revealed a 6.2 fold preference for axial formation of the new C-O-bond.This preference dominates the 3.1 fold preference for an exo-versus endo-tran

Stereoselective Synthesis of Alcohols, I Synthesis of One-Carbon Homologous Allyl Alcohols from Aldehydes or Ketones

The high yield conversion of aldehydes and ketones 2 to the one-carbon homologous allyl alcohols 3 is achieved by condensation to the vinyl sulfoxides 7, isomerisation to the allyl sulfoxides 9, and subsequent sigmatropic rearrangement.