73958-83-5Relevant academic research and scientific papers
NEW CHELATE RING OPENING REACTIONS LEADING TO THE SYNTHESIS OF NOVEL MIXED LIGAND COMPLEXES OF THE OCTAHEDRAL METAL CARBONYLS
KING, R. B.,LEE, T. W.
, p. C17 - C20 (2007/10/02)
Reactions of the four-membered ring chelate CH3N(PF2)2Cr(CO)4 with trivalent phosphorus ligand (L) at 80 deg C leads to facile opening of the chelate ring to give the mixed ligand complexes trans-CH3N(PF2)2Cr(CO)4L (L=C6H5)3P or monodentate C6H5(PF2)2) containing a monodentate CH3N(PF2)2 ligand.
