7399-24-8Relevant academic research and scientific papers
Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes
Kato,Yamada,Takai,Inoki,Isayama
, p. 179 - 186 (2007/10/02)
In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (''oxidation-reduction hydration''). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)2) or bis(2-ethoxycarbonyl-3-oxobutanalato)-cobalt(II) (Co(ecbo)2).
Identification of the Aggregation Pheromone of Flour Beetles Tribolium castaneum and T. confusum (Coleoptera: Tenebrionidae)
Suzuki, Takahisa
, p. 1357 - 1364 (2007/10/02)
The aggregation pheromone produced by the male red flour beetle Tribolium castaneum, and confused flour beetles, T. confusum was identified as 4,8-dimethyldecan-1-al by GLC, GC-MS, PMR spectra, and synthesis of the compound.The synthetic pheromone was less attractive compared with the natural pheromone, because the synthetic sample was composed of four optical isomers.
