74005-15-5

Basic information

• Product Name: dicarbonyl[1,3-bis(phenylphosphino)propane]nickel⁽⁰⁾
• Synonyms: dicarbonyl[1,3-bis(phenylphosphino)propane]nickel⁽⁰⁾
• CAS NO: 74005-15-5
• Molecular Weight: 374.966
• Mol File: 74005-15-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dicarbonyl[1,3-bis(phenylphosphino)propane]nickel⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: dicarbonyl[1,3-bis(phenylphosphino)propane]nickel⁽⁰⁾(74005-15-5)
• EPA Substance Registry System: dicarbonyl[1,3-bis(phenylphosphino)propane]nickel⁽⁰⁾(74005-15-5)

Safety Data

• Hazardous Substances Data: 74005-15-5(Hazardous Substances Data)

Upstream product

• 13463-39-3 tetracarbonyl nickel 
• 28240-66-6 1,3-bis(phenylphosphano)propane 

Relevant articles and documents

Reactions of Coordinated Ligands, VIII. Synthesis, Reactivity and Structure of Molybdenum- and Nickel Carbonyl Complexes of 1,3-Bis(phenylphosphino)propane

1,3-Bis(phenylphosphino)propane reacts with Ni(CO)4, C7H8Mo(CO)4, and Mo(CO)6 to produce complexes of the type (CO)nM(PhPH - C3H6 - PPhH) (n = 4, M = Mo; n = 2, M = Ni) and oligomers thereof.These compounds were also obtained by the reaction of phosphido complexes (CO)nM(PhPHM')2 (n = 4, M = Mo, M' = Li; n = 2, M = Ni, M' = Li, Na) with 1,3-dibromopropane.The complexes (CO)nM(PhPH - C3H6 - PPhH) may be deprotonated with methyllithium.The reactions of the phosphido complexes thus obtained are discussed.From the meso-form of (CO)2Ni(PhPH - C3H6 - PPhH), which crystallizes in the space group Cmc21, an x-ray structure anal ysis has been performed.