74005-16-6

Upstream product

• 74005-17-7 tetracarbonyl(1,3-bis[phenyl(trimethylsilyl)phosphino]propane)molybdenum⁽⁰⁾ 
• 109-64-8 1,3-dibromo-propane 
• 12146-37-1 (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾ 
• 28240-66-6 1,3-bis(phenylphosphano)propane 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 74005-18-8 cis-tetracarbonyl(1,5,9,13-tetraphenyl-1,5,9,13-tetraphosphacyclohexadecane-1,5-dioxide-P⁽⁹⁾,P⁽¹³⁾)molybdenum⁽⁰⁾ 
• 74005-17-7 tetracarbonyl(1,3-bis[phenyl(trimethylsilyl)phosphino]propane)molybdenum⁽⁰⁾ 
• 74005-19-9 (1,5,9,13-tetraphenyl-1,5,9,13-tetraphosphatridecane-P(1,5):P(9,13))bis[cis-tetracarbonylmolybdenum⁽⁰⁾] 

Relevant academic research and scientific papers

Synthesis, spectroscopic and structural characterisation of chromium(0), molybdenum(0) and tungsten(0) complexes involving primary and secondary phosphines

[M(CO)6] (M=Mo or W) reacts with 4.5 molar equivalents of L (L=PPh2H or PPhH2) in excess ethanolic NaBH4 to yield the fac-trisubstituted species [M(CO)3(L)3] in good yield, with no evidence

Reactions of Coordinated Ligands, VIII. Synthesis, Reactivity and Structure of Molybdenum- and Nickel Carbonyl Complexes of 1,3-Bis(phenylphosphino)propane

1,3-Bis(phenylphosphino)propane reacts with Ni(CO)4, C7H8Mo(CO)4, and Mo(CO)6 to produce complexes of the type (CO)nM(PhPH - C3H6 - PPhH) (n = 4, M = Mo; n = 2, M = Ni) and oligomers thereof.These compounds were also obtained by the reaction of phosphido complexes (CO)nM(PhPHM')2 (n = 4, M = Mo, M' = Li; n = 2, M = Ni, M' = Li, Na) with 1,3-dibromopropane.The complexes (CO)nM(PhPH - C3H6 - PPhH) may be deprotonated with methyllithium.The reactions of the phosphido complexes thus obtained are discussed.From the meso-form of (CO)2Ni(PhPH - C3H6 - PPhH), which crystallizes in the space group Cmc21, an x-ray structure anal ysis has been performed.