74027-98-8Relevant articles and documents
One-step chemoselective conversion of tetrahydropyranyl ethers to silyl-protected alcohols
Bergueiro, Julian,Montenegro, Javier,Saa, Carlos,Lopez, Susana
, p. 14475 - 14479 (2014/04/17)
Aluminium trichloride catalyses the expeditious direct conversion of tetrahydropyranyl ethers to silyl ethers. This one-step transformation is chemoselective versus deprotection of the acetal and hydrosilylation of unsaturated carbon-carbon bonds, and can also be applied to linear acetals. A possible mechanism is tentatively proposed. This journal is the Partner Organisations 2014.