74077-06-8

Basic information

• Product Name: 1,2-Dimethyl-cis-1,2-cyclohexandiol-bis(trifluoracetat)
• CAS NO: 74077-06-8
• Molecular Weight: 336.231
• Mol File: 74077-06-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Dimethyl-cis-1,2-cyclohexandiol-bis(trifluoracetat)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Dimethyl-cis-1,2-cyclohexandiol-bis(trifluoracetat)(74077-06-8)
• EPA Substance Registry System: 1,2-Dimethyl-cis-1,2-cyclohexandiol-bis(trifluoracetat)(74077-06-8)

Safety Data

• Hazardous Substances Data: 74077-06-8(Hazardous Substances Data)

Upstream product

• 14353-86-7 iodine tris(trifluoroacetate) 
• 1674-10-8 1,2-dimethylcyclohexene 

Relevant articles and documents

Oxidation of Alkenes by Iodine Tris(trifluoroacetate). On the cis-Effect of the Trifluoroacetate Group in Oxidations

Iodine tris(trifluoroacetate) oxidizes alkenes to α-glycol bis(trifluoroacetates) (eq. (1) and tab. 1).By-products are acylals emerging out of a 1,2-shift (eq. (3)). 1,2-Disubstituted alkenes are mainly transformed into cis-glycol derivatives and tri- and tetrasubstituted alkenes to cis/trans mixtures.The oxidations proceed via 2-acyloxy-1,3-dioxolanes, formerly postulated by Winstein et al. as intermediates in similar oxidations, but only now isolated (comp. 3) and examined by NMR and rearranged to the corresponding α-glycols (3 -> 5).A similar reaction course isproposed for certain other alkene oxidations known from literature, in which a trifluoroacetate group is involved and which proceed under cis-addition (table 3).