740809-95-4Relevant academic research and scientific papers
Different recognitions of (E)- and (Z)-1,1′-binaphthyl ketoximes using lipase-catalyzed reactions
Aoyagi, Naoto,Kawauchi, Shinji,Izumi, Taeko
, p. 5189 - 5192 (2007/10/03)
Lipase-catalyzed hydrolysis of (E)-2-[α-(acetoxyimino)benzyl]-1, 1′-binaphthyl [(±)-1a] and (Z)-2-[α-(acetoxyimino)benzyl]-1, 1′-binaphthyl [(±)-1b] yielded optically active (E)-2-[α-(hydroxyimino)benzyl]-1,1′-binaphthyl [(S)-2a] and (Z)-2-[α-(hydroxyimino)benzyl]-1,1′-binaphthyl [(R)-2b], respectively, with high enantiomeric excess. Selectivity for the opposite enantiomer of the axial binaphthyl skeleton was shown by (Z)-isomer 1b against (E)-isomer 1a.
