74087-87-9Relevant articles and documents
A Fourier Transform Infrared Study of the Kinetics and Mechanism for the Reaction HO + CH3OOH
Niki, H.,Maker, P. D.,Savage,C. M.,Breitenbach, L. P.
, p. 2190 - 2193 (2007/10/02)
The analysis of products in the photolysis of mixtures containing C2H5ONO, NO, and CH3OOH in ppm concentrations in 700 torr of O2-N2 diluent by FT IR is consistent with a value of (k1a/k1b) = 0.77 (+/-20percent) for the competitive H-abstraction channels HO + CH3OOH -> CH2OOH + H2O (1a) and -> CH3OO + H2O (1b).An absolute value of (k1a + k1b) = 1.0 * 10-11 cm3 molecule-1 s-1 was derived from the decay rates of CH3OOH relative to those of C2H4 and CH3CHO.