74098-25-2Relevant academic research and scientific papers
The Heck-type arylation of allylic alcohols with arenediazonium salts
Masllorens, Judit,Bouquillon, Sandrine,Roglans, Anna,Hénin, Fran?oise,Muzart, Jacques
, p. 3822 - 3826 (2005)
The Heck coupling of ArN2BF4 with secondary allylic alcohols, carried out in methanol using Pd(dba)2 as catalyst without extra ligands and base, leads to the corresponding β-arylated carbonyl compounds. Such conditions afford arylated acetals from primary allylic alcohols.
New Methods and Reagents in Organic Synthesis; 73. Trimethylsilyldiazomethane: A Convenient Reagent for the Conversion of Aliphatic Aldehydes to the Homologous Methyl Ketones
Aoyama, Toyohiko,Shioiri, Takayuki
, p. 228 - 229 (2007/10/02)
Trimethylsilyldiazomethane reacts smoothly with aliphatic aldehydes in the presence of magnesium bromide (1.5 eqiv) to give homologous methyl ketones after direct treatment with 10percent hydrochloric acid/methanol (1:1).
