7410-60-8Relevant academic research and scientific papers
Specificity of salicylaldehyde S-alkylisothiosemicarbazones coordination in palladium(II) complexes
Revenco, Mihail,Bulmaga, Petru,Jora, Elena,Palamarciuc, Oleg,Kravtsov, Victor,Bourosh, Paulina
, p. 250 - 255 (2014)
S-alkylated salicylaldehyde thiosemicarbazones (HL) form with palladium(II) the complexes 1-3 of the general formula [Pd(L)Cl], where L is monodeprotonated S-ethyl- for 1, S-heptyl- for 2, and S-isopropyl- for 3 derivatives of HL. 5-Bromosalicyladehyde S-
A uranium(VI) complex with a tetradentate N1,N4-disalicyliden-S-ethylisothiosemicarbazone ligand
Akbari, Alireza,Fasihizad, Ahad,Ahmadi, Mehdi,Machura, Barbara
, p. 188 - 197 (2017)
The Schiff base ligand of bis-(2-hydroxybenzaldehyde)-S-ethylisothiosemicarbazone and its U(VI) complex have been prepared. Their structures were fully characterized by elemental analysis, FT-IR, molar conductivity, UV–Vis and 1H NMR methods. X-ray diffraction has been used to determine the molecular structure of the uranium complex. The Schiff base complex was found to be pentagonal bipyramidal. The N2O2 donor ligand was coordinated to the metal center as a tetradentate binegative agent. Computational studies were performed using the DFT method to estimate the structural preferences in tridentate and tetradentate isothiosemicarbazones. Geometry optimization and natural bond orbital analyses of the UO2(II) complex have been further discussed in detail. The thermal stabilities of the ligand and its uranium complex have also been determined by thermogravimetric analysis (TGA).
