74104-18-0Relevant academic research and scientific papers
METHYLENATIONS OF HETEROATOM-SUBSTITUTED CARBONYLS WITH DIMETHYL TITANOCENE
Petasis, Nicos A.,Lu, Shao-Po
, p. 2393 - 2396 (1995)
Reaction of dimethyl titanocene with a variety of heteroatom-substituted carbonyl compounds, including: silylesters, anhydrides, carbonates, amides, imides, thioesters, selenoesters and acyl silanes gives the corresponding heteroatom-substituted alkenes.
The Stereoselective Synthesis of α,β-Unsaturated Ketones by the Stepwise Cross-Coupling Reaction of -(2-Bromoethenyl)diisopropoxyborane
Ogima, Masahiko,Hyuga, Satoshi,Hara, Shoji,Suzuki, Akira
, p. 1959 - 1962 (2007/10/02)
The palladium catalyzed stepwise cross-coupling reaction of (E)-(2-bromoethenyl)diisopropoxyborane, readily available by bromoboration of acetylene, with α-alkoxyalkenylzinc chlorides and organic halides gives α,β-unsaturated ketones in good yields with high (E)-selectivity.
