741271-18-1Relevant academic research and scientific papers
Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters
Wagh, Sachin Bhausaheb,Liu, Rai-Shung
supporting information, p. 15462 - 15464 (2015/10/20)
Gold-catalyzed synthesis of buta-1,3-dien-2-yl esters by the reaction of propargyl esters with vinylazides is described; the reaction mechanism is postulated to involve a vinyl attack of vinylazides at alkenyl gold carbenes.
Platinum(II) chloride catalyzed cycloisomerizations of 1,5-enynes
Blaszykowski, Christophe,Harrak, Youssef,Brancour, Celia,Nakama, Kimitaka,Dhimane, Anne-Lise,Fensterbank, Louis,Malacria, Max
, p. 2037 - 2049 (2008/02/11)
1,5-Enynes are highly reactive under PtCl2 catalysis and give a range of [3.1.0] bicyclic skeletons. The scope and limitations of this process are presented. Regioisomeric keto derivatives are obtained depending upon the nature of the oxygenate
