74134-56-8Relevant articles and documents
SYNTHESIS AND CHARACTERIZATION OF ALKYL-, HALO- AND HETEROSUBSTITUTED DERIVATIVES OF THE POTENT PHOTOTOXIN &α-TERTHIENYL
Eachern, Anita Mac,Soucy, Chantal,Leitch, Leonard C.,Arnason, John T.,Morand, Peter
, p. 2403 - 2412 (2007/10/02)
A number of derivatives of α-terthienyl were prepared including a series of naturally occurring compounds.A description of the syntheses of some new compounds, including 5-iodo, 5,5''-diiodo, 5,5''-diformyl, 5,5''-di-tert butyl, 5-tert-butyl, 5-tert-butoxy, 5-trimethylsilyl, 5-thiomethyl, 5,5''-dithiomethyl and 5-carboxyl-5''-(trimethylsilyl)-2,2':5',2''-terthienyl is also given.An analysis of the 1H NMR data of the derivatives is presented.
5-(2,3-DIPHENYLCYCLOPROPENYLIDENE)-2(5H)-THIOPHENONE CHARACTERIZATION OF A THIOPHENE-INSERTED TYPE COMPOUND OF DIPHENYLCYCLOPROPENONE
Takahashi, Kazuko,Nishijima, Kazumi,Takase, Kahei,Katagiri, Shigeyoshi
, p. 205 - 208 (2007/10/02)
The title compound 6 has been synthesized and the effect of cyclic ?-system insertion into diphenylcyclopropenone 1 has been discussed.The distribution of positive charge over the 3-membd. ring and phenyl groups slightly predominates in 6 than in parent annulenone 1, in contrast to 5-cycloheptatrienylidene-2(5H)-tiophenone 5 whose 7-membd. ring is more olefinic than parent tropone 2.Electronic spectrum of 6 exhibits a broad absorption band having a C-T character.