74142-35-1Relevant articles and documents
VINYL CATIONS 33: 1-ALKENE-3-YNE-2-YL TRIFLATES, PRECURSORS OF TRIPLE BOND STABILIZED VINYL CATIONS-SYNTHESIS AND FIRST SOLVOLYTIC STUDIES.
Hassdenteufel, Juergen Rolf,Hanack, Michael
, p. 503 - 506 (2007/10/02)
The α-alkynyl vinyl triflates (3) are synthesized and the solvolyses reactions studied in different solvents.The solvolysis products and kinetic data indicate, that the hitherto unknown triple bond stabilized vinyl cation 2a 2b is formed as an intermediate.