74179-27-4

Basic information

• Product Name: Benzofuran, 2,2,3,3a,4,4,5,5,6,6,7,7,7a-tridecafluorooctahydro-3-(pentafluoroethyl)-
• CAS NO: 74179-27-4
• Molecular Formula: C10F18O
• Molecular Weight: 478.081
• Mol File: 74179-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzofuran, 2,2,3,3a,4,4,5,5,6,6,7,7,7a-tridecafluorooctahydro-3-(pentafluoroethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzofuran, 2,2,3,3a,4,4,5,5,6,6,7,7,7a-tridecafluorooctahydro-3-(pentafluoroethyl)-(74179-27-4)
• EPA Substance Registry System: Benzofuran, 2,2,3,3a,4,4,5,5,6,6,7,7,7a-tridecafluorooctahydro-3-(pentafluoroethyl)-(74179-27-4)

Safety Data

• Hazardous Substances Data: 74179-27-4(Hazardous Substances Data)

Upstream product

• 74179-26-3 methyl 2-cyclohexen-2-yl-n-butyrate 

Relevant articles and documents

SYNTHESIS OF PERFLUOROBICYCLIC ETHERS . THE ELECTROCHEMICAL FLUORINATION OF α-CYCLOHEXENYL-SUBSTITUTED CARBOXYLIC ACID DERIVATIVES

The electrochemical fluorination of α-cyclohexenyl-substituted carboxylic esters afforded both perfluoro (9-alkyl-7-oxa-bicyclononane)s and perfluoro(8-alkoxy-9-alkyl-7-oxabicyclononane)s in fairly good yields.As the driving force for the ring-closure in this fluorination, a mechanism which involves a resonance stabilized intermediate radical is proposed. Perfluoro(8-chloro-8-methoxy-9-ethyl-7-oxabicyclononane) and perfluoro(8,8-dichloro-9-ethyl-7-oxabicyclononane) were obtained by the controlled chlorination of perfluoro(8-methoxy-9-ethyl-7-oxabicyclo nonane) with anhydrous aluminum chloride in low yields.Some new fused perfluorobicyclic ethers and a perfluoroacid fluoride obtained in this experiment have been characterized by infrared, mass and 19F nmr spectra and elemental analysis.