74181-88-7

Upstream product

• 74145-63-4 (3aβ,3bα,6aα)-3,3a,3b,5,6,6a-hexahydro-3,3a,5,5-tetramethylcyclopenta<4,5>pentalene-2,4-dione 
• 74145-62-3 (3aβ,3bα,6aα)-3a,3b,5,6,6a,7-hexahydro-3,3a,5,5-tetramethylcyclopenta<4,5>pentalene-2,4-dione 
• 74145-61-2 (3aR,6S,6aR)-2,2,6-Trimethyl-6-(1-methyl-2-oxo-propyl)-hexahydro-pentalene-1,5-dione 
• 73114-15-5 phenyl(thiophenyl)sulfonate 
• 74181-87-6 (3ε,3aβ,3bα,4α,6aα,7β)-3a,3b,5,6,6a,7-hexahydro-3,3a,5,5-tetramethyl-4,7-dihydroxy-3-(phenylthio)-4H-cyclopenta<4,5>pentalen-2-one 
• 74145-67-8 (4aβ,4bα,5α,7aα,7bα)-4,4a,4b,5,6,7,7a,7b-octahydro-4,4a,6,6-tetramethyl-5-hydroxycyclopenta<4,5>pentaleno<6,6a-b>oxiren-3-one 
• 74145-64-5 (3aR,3bS,7aR)-5-Hydroxy-2,2,3b,4-tetramethyl-1,2,3a,3b,4,5,6,7a-octahydro-cyclopenta[a]pentalen-3-one 
• 74145-65-6 (3aS,3bR,4R,6aR)-3,3a,5,5-Tetramethyl-2,3,3a,3b,4,5,6,6a-octahydro-1H-cyclopenta[a]pentalene-2,4-diol 
• 74145-66-7 C₁₅H₂₄O₃ 
• 1212-08-4 S-Phenyl benzenethiosulfonate 

Downstream Products

• 33404-85-2 dl-coriolin 
• 33404-85-2 C₁₅H₂₀O₅ 
• 33400-89-4 dl coriolin B 
• 33404-85-2 dl-coriolin 
• 33404-85-2 3-epicoriolin 

Relevant academic research and scientific papers

Stereospecific Total Synthesis of dl-Coriolin and dl-Coriolin B

The total synthesis of the title compounds are described.The starting materials were the enedione 6 and the siloxy diene 27.Cycloaddition of these compounds afforded 28, which was converted to 30.Degradation of enone 30 gave methyl ketone 32, which upon c