74190-43-5Relevant academic research and scientific papers
Organocatalytic asymmetric Michael addition of 1-acetylcyclohexene and 1-acetylcyclopentene to nitroolefins
Nath, Utpal,Banerjee, Ankush,Ghosh, Bidhan,Pan, Subhas Chandra
, p. 7076 - 7083 (2015/06/25)
Enantioselective organocatalytic Michael addition reactions of 1-acetylcyclohexene, 1-acetylcyclopentene and 1-acetylcyclobutene to nitroolefins have been developed. This is the first report where an α-branched enone has been activated by an amine catalyst for the asymmetric Michael addition reaction to an electrophile. The Michael products have also been cyclized to bicyclic compounds.
