74205-92-8Relevant academic research and scientific papers
Synthesis and study of thermal stability of 3-nitro-1,2,4-triazole N-nitroxy- and N-azidomethyl derivatives
Tselinskii,Tolstyakov,Putis,MeVnikova
, p. 2356 - 2361 (2009)
A method for the preparation of new 3-nitro-1,2,4-triazole derivatives has been suggested based on modification of the N-hydroxymethyl group by nitration and nucleophilic substitution reactions. Thermal stability of 3-nitro-1,2,4-triazole N-nitroxy- and N
HETEROCYCLIC NITRO COMPOUNDS. 25. 1-HYDROXYMETHYL-3-NITRO-1,2,4-TRIAZOLES AND THEIR DERIVATIVES
Pevzner, M. S.,Ivanov, P. A.,Gladkova, N. V.,Sushchenko, O.N.,Tverdokhlebov, V. P.,Myasnikova, Z. S.
, p. 189 - 194 (2007/10/02)
1-Hydroxymethyl derivatives of tetrazoles were obtained by the reaction of 1,2,4-triazole and 3-nitro-5-substituted triazoles with formaldehyde in water.The hydroxy groups were replaced by chlorine, and the hydroxymethyltriazoles were acetylated and tosylated.The chloro and tosyl groups are readily replaced by iodine by the action of potassium and ammonium iodide in acetone.
