742086-24-4Relevant academic research and scientific papers
Syntheses and structures of Ag(I)-containing coordination polymers and Co(II)-containing supramolecular complex based on novel fulvene ligands
Dong, Yu-Bin,Wang, Peng,Huang, Ru-Qi,Smith, Mark D.
, p. 4727 - 4739 (2004)
Three new rigid conjugated fulvene ligands L1-L3 were synthesized. L1 and L3 have been prepared by an aroylation reaction of cyclohexyl-substituted cyclopentadienyl anions. L2 was prepared by the reaction of L1 with PhNHNH 2 in hot enthanol. Six new coordination polymers, namely [Ag(C 25H20N2O2)(ClO4) ·3.5C6H6 (1), [Ag2(μ-C 31H24N4)(η2-C6H 6)(H2O)](ClO4)2·(C 6H6)·(H2O)0.5 (3), [Ag(C 31H24N4)]SbF6·solvate (4), [Ag(C31H24N4)](SbF6) 2·2C6H6·CH2Cl 2 (5), [Ag(C25H20N2O 2)2]SbF6 (6), and [Ag(C25H 20N2O2)2]SbF6 (7), and one seven-membered cobaltacycle-containing complex, namely Co(C 25H20N2O2)2(C 2H5OH)2 (2), were obtained through self-assembly based on these three new fulvene lignads. L2-L3 and compounds 1-7 have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The results indicate that the coordination chemistry of new fulvene ligands is versatile. They can bind metal ions not only through the terminal N-donors and fulvene carbon atoms into organometallic coordination polymers but also through the two chelating carbonyl groups into unusual seven-membered metallo-ring supramolecular complexes. In the solid state, ligands L1-L3 are luminescent. A blue-shift in the emission was observed between the free ligand L1 and the one incorporated into Co(II)-containing complex 2, and a red-shift in the emission was observed between the free ligand L3 and the one incorporated into Ag(I)-containing polymeric compounds 6 and 7.
