74209-84-0Relevant academic research and scientific papers
DIASTEREOSELECTIVE ALDOL SYNTHESIS USING ACETAL TEMPLATES
Ishihara, Kazuaki,Yamamoto, Hisashi,Heathcock, Clayton H.
, p. 1825 - 1828 (2007/10/02)
Stereoselectivity of the Mukaiyama reaction is dramatically changed by the steric features of acetal structures.
TRIMETHYLSILYL TRIFLATE CATALYZED ALDOL-TYPE REACTION OF ENOL SILYL ETHERS AND ACETALS OR RELATED COMPOUNDS
Murata, Shizuaki,Suzuki, Chikusa,Noyori, Ryoji
, p. 4259 - 4276 (2007/10/02)
Trimethylsilyl triflate with or without added hindered tertiary amines catalyzes directed condensation of enol trimethylsilyl ethers with acetals, orthoformate, or 2-acetoxytetrahydrofuran or -pyrans to give the corresponding β-alkoxy carbonyl compounds.R
TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS
Noyori, R.,Murata, S.,Suzuki, M.
, p. 3899 - 3910 (2007/10/02)
Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.
