74233-07-1

Basic information

• Product Name: 2-tert-Butyl-4-hydroperoxy-4-methyl-cyclohexa-2,5-dienone
• Synonyms: 2-tert-Butyl-4-hydroperoxy-4-methyl-cyclohexa-2,5-dienone
• CAS NO: 74233-07-1
• Molecular Weight: 196.246
• Mol File: 74233-07-1.mol

Chemical Properties

• CAS DataBase Reference: 2-tert-Butyl-4-hydroperoxy-4-methyl-cyclohexa-2,5-dienone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-tert-Butyl-4-hydroperoxy-4-methyl-cyclohexa-2,5-dienone(74233-07-1)
• EPA Substance Registry System: 2-tert-Butyl-4-hydroperoxy-4-methyl-cyclohexa-2,5-dienone(74233-07-1)

Safety Data

• Hazardous Substances Data: 74233-07-1(Hazardous Substances Data)

Upstream product

• 2409-55-4 2-tert-Butyl-4-methylphenol 

Relevant articles and documents

Oxidative photocatalytic homo- And cross-coupling of phenols: Nonenzymatic, catalytic method for coupling tyrosine

An oxidative photocatalytic method for phenol? phenol homo- and cross-coupling is described, and isolated yields of 16?97% are obtained. Measured oxidation potentials and computed nucleophilicity parameters support a mechanism of nucleophilic attack of one partner onto the oxidized neutral radical form of the other partner. Our understanding of this model permitted the development of cross-coupling reactions between nucleophilic phenols/arenes and easily oxidized phenols with high selectivity and efficiency. A highlight of this method is that one equivalent of each coupling partner is utilized. Building on these findings, a nonenzymatic, catalytic method for coupling tyrosine was also developed.