74234-76-7Relevant academic research and scientific papers
The Acid-catalyzed Reaction of the 2-Oxabicyclohept-3-en-5-one System: Isomerization from Homo-4-pyrones into 2-Furylacetone Derivatives
Yamaoka, Hiroshi,Mishima, Ikuhiro,Miyamoto, Mitsuko,Hanafusa, Terukiyo
, p. 469 - 477 (1980)
The monocyclopropanation of 4-pyrones with dimethyloxosulfonium methylide, using a dimethyl sulfoxidehexamethylphosphoric triamide medium in place of neat dimethyl sulfoxide, gave homo-4-pyrone derivatives, which were then rearranged into the 2-furylacetone derivatives, along with hydrated triketones or the dehydrated naphthofuran derivative, by means of strong acid catalysis at room temperature.
